cat converter is rarely the problem, usually it's due to incomplete combustion. do a reasearch on google how to pass the smog test.
usually you would start with replacing all filters, plugs, wires, distributor rotor, clean the throttle body, check or replace the oxygen sensor, change oil! thats a big one, and have the fresh fuel in the tank before taking the test.
also make sure the car is really warmed up as even newer cars will fail the test when cold.
good luck.